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(S)-Glycidol
Product Name:(S)-oxiran-2-ylmethanol
Synonyms:(S)-(-)-2,3-Epoxy-1-propanol, (S)-(-)-Oxirane-2-methanol;(S)-Glycidol;(S)-()-2,3-Epoxy-1-propanol, (S)-()-Oxirane-2-methanol;(S)-(-)-Glycidol
CAS number:[60456-23-7]
MDL Number:MFCD00074874
MF:C3H6O2
Smile:OC[C@@H]1OC1
InChI=1S/C3H6O2/c4-1-3-2-5-3/h3-4H,1-2H2/t3-/m0/s1
InChiKey:CTKINSOISVBQLD-VKHMYHEASA-N

SPECIFICATIONS & PROPERTIES
Purity:99% (GC), ee 98% (Chiral GC)
Available Spectra:NMR, GCMS, FT-IR, GC, Chiral GC, Polarimetry
Physical Form:Colorless to light yellow liquid
Boiling Point:66-67 C (19 mmHg)
Flash Point:66 C
Optical Rotation:-15 (+)2 (neat)
Density:1.116-1.123
Refractive Index:1.431-1.435
Long-Term Storage:Store long-term at -20ˇăC

CATEGORIES:chiral;API intermediates;CHIRAL COMPOUNDS;Chiral Compound

REFERENCES
[1] Rider, T.H. et al. , J.A.C.S. , 1930, 52 , 1521
[2] Flores-Gallardo, H. et al. , J.O.C. , 1947, 12 , 831-833

GHS Hazard Codes & Statements
UN #:UN2810
Hazard Class:6.1
Packing Group:III
Signal Word:Danger
Hazard Statements:H227; H302+H312; H315; H318; H331; H335; H350; H360
Precuationary Statements:
P201; P202; P210; P261; P264; P270; P271; P280; P302+P352; P304+P340; P305+P351+P338; P310; P322; P330; P332+P313; P362; P370+P378; P403+P233; P403+P235; P405; P501 GHS description

Related Product Information
Ethylene glycol diglycidyl ether DIGLYCIDYL ETHER 1-Propanol Phenolic epoxy resin ETHYLENE OXIDE 1,2,3-PROPANETRIOL GLYCIDYL ETHER (2R)-(-)-2-METHYLGLYCIDYL 4-NITROBENZOATE (S)-Oxiranemethanol 4-methylbenzenesulfonate,OXIRANEMETHANOL, 4-METHYLBENZENESULFONATE, (2R)-,(R)-OXIRANEMETHANOL 4-METHYLBENZENESULFONATE,Oxiranemethanol, 4-methylbenzenesulfonate, (R)- (R)-(-)-Glycidyl nosylate RORIDIN A (2R)-(-)-GLYCIDYL 4-NITROBENZOATE (2R,3S)-(+)-3-(BENZYLOXYMETHYL)OXIRANE-2-METHANOL 4-NITROBENZOIC ACID ESTER PICROSIDE I (S)-Oxiranemethanol Resin epoxy BISPHENOL A DIGLYCIDYL ETHER RESIN Methanol GLYCIDALDEHYDE

Synthesis Route referencs
Shapiro, M.J. , J.O.C. , 1977, 42 , 1434
Wyrick, S.D. et al. , J. Med. Chem. , 1978, 21 , 368-390
DiMenna, W.S. et al. , J. Med. Chem. , 1978, 21 , 1073-1076
Brown, R.M. et al. , Org. Mass Spectrom. , 1980, 15 , 578-581
Garrido Espinasa, F. et al. , An. Quim., Ser. C , 1981, 77 , 22-27
Hirth, G. et al. , Helv. Chim. Acta , 1982, 65 , 1059-1084
Mouzin, G. et al. , Synthesis , 1983, 117-119
Vandenberg, E.J. et al. , J. Polym. Sci., Polym. Chem. Ed. , 1985, 23 , 915
Miyano, S. et al. , J.O.C. , 1985, 50 , 4350-4360
Gao, Y. et al. , J.A.C.S. , 1987, 109 , 5765
Burgos, C.E. et al. , J.O.C. , 1987, 52 , 4973